|CAS Number||UN/NA Number|
|DOT Hazard Label||USCG CHRIS Code|
|NIOSH Pocket Guide||International Chem Safety Card|
|Health||2||Can cause temporary incapacitation or residual injury.|
|Flammability||3||Can be ignited under almost all ambient temperature conditions.|
|Instability||1||Normally stable but can become unstable at elevated temperatures and pressures.|
- Highly Flammable
- Peroxidizable Compound
Behavior in Fire: May explode. Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. (USCG, 1999)
No information available.
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient. CAUTION: For fire involving UN1170, UN1987 or UN3475, alcohol-resistant foam should be used. CAUTION: Ethanol (UN1170) can burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.).
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. Avoid aiming straight or solid streams directly onto the product. If it can be done safely, move undamaged containers away from the area around the fire.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. A vapor-suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean, non-sparking tools to collect absorbed material.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor, but may not prevent ignition in closed spaces. (ERG, 2020)
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: WHEN CONTAMINATED - The worker should immediately wash the skin when it becomes contaminated.
Remove: WHEN WET (FLAMMABLE) - Work clothing that becomes wet should be immediately removed due to its flammability hazard (i.e., for liquids with a flash point <100°F).
Change: No recommendation is made specifying the need for the worker to change clothing after the workshift. (NIOSH, 2022)
|QS = Tychem 2000 SFR|
|QC = Tychem 2000|
|SL = Tychem 4000|
|C3 = Tychem 5000|
|TF = Tychem 6000|
|TP = Tychem 6000 FR|
|RC = Tychem RESPONDER® CSM|
|TK = Tychem 10000|
|RF = Tychem 10000 FR|
"imm" indicates immediate; having a normalized breakthrough time of 10 minutes or less.
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...
SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
INGESTION: DO NOT INDUCE VOMITING. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. IMMEDIATELY transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)
AEGLs (Acute Exposure Guideline Levels)No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
|Tetrahydrofuran (109-99-9)||100 ppm||500 ppm||5000 ppm||LEL = 18000 ppm|
indicates value is 10-49% of LEL.
PACs (Protective Action Criteria)
|Tetrahydrofuran (109-99-9)||100 ppm||500 ppm||5000 ppm||LEL = 20000 ppm|
EPA Consolidated List of Lists
|Regulatory Name||CAS Number/
313 Category Code
|CERCLA RQ||EPCRA 313
|Furan, tetrahydro-||109-99-9||1000 pounds||U213|
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)No regulatory information available.
OSHA Process Safety Management (PSM) Standard ListNo regulatory information available.
- BUTANE ALPHA,DELTA-OXIDE
- BUTANE, 1,4-EPOXY-
- BUTYLENE OXIDE
- CYCLOTETRAMETHYLENE OXIDE
- DIETHYLENE OXIDE
- FURAN, TETRAHYDRO-
- TETRAMETHYLENE OXIDE
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