HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE
|CAS Number||UN/NA Number|
|DOT Hazard Label||USCG CHRIS Code|
|NIOSH Pocket Guide||International Chem Safety Card|
|Health||3||Can cause serious or permanent injury.|
|Flammability||0||Will not burn under typical fire conditions.|
|Instability||3||Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation.|
|Special||OX||Possesses oxidizing properties.|
- Strong Oxidizing Agent
May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2020)
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire may produce irritating and/or toxic gases. Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2020)
Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...
- Cellulose-Based Absorbents
- Expanded Polymeric Absorbents
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
SMALL FIRE: Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
LARGE FIRE: Flood fire area with water from a distance. Do not move cargo or vehicle if cargo has been exposed to heat. If it can be done safely, move undamaged containers away from the area around the fire. Do not get water inside containers: a violent reaction may occur.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well after fire is out. Dike runoff from fire control for later disposal. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2020)
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewers, basements or confined areas.
SMALL SPILL: Flush area with large amounts of water.
LARGE SPILL: DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST. (ERG, 2020)
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2020)
|QS = Tychem 2000 SFR|
|QC = Tychem 2000|
|SL = Tychem 4000|
|C3 = Tychem 5000|
|TF = Tychem 6000|
|TP = Tychem 6000 FR|
|RC = Tychem RESPONDER® CSM|
|TK = Tychem 10000|
|RF = Tychem 10000 FR|
|Hydrogen peroxide (30%)||7722-84-1||Liquid||>480||>480||>480||>480|
|Hydrogen peroxide (50%)||7722-84-1||Liquid||>480||>480||>480||>480|
|Hydrogen peroxide (70%)||7722-84-1||Liquid||>480||>480||>480||>480||>480||>480||>480|
Special Warning from DuPont: Tychem® and Tyvek® fabrics should not be used around heat, flames, sparks or in potentially flammable or explosive environments. Only...
Call 911 or emergency medical service. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air if it can be done safely. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. Contaminated clothing may be a fire risk when dry. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. Keep victim calm and warm. (ERG, 2020)
AEGLs (Acute Exposure Guideline Levels)No AEGL information available.
ERPGs (Emergency Response Planning Guidelines)
|Hydrogen Peroxide (7722-84-1)||10 ppm||50 ppm||100 ppm|
PACs (Protective Action Criteria)
|Hydrogen peroxide (7722-84-1)||10 ppm||50 ppm||100 ppm|
EPA Consolidated List of Lists
|Regulatory Name||CAS Number/
313 Category Code
|CERCLA RQ||EPCRA 313
|Hydrogen peroxide (Conc.> 52%)||7722-84-1||1000 pounds||1000 pounds|
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
|Chemical of Interest||CAS Number||Min Conc||STQ||Security
|Hydrogen peroxide (concentration of at least 35%)||7722-84-1||35.00 %||400 pounds||EXP/IEDP|
- EXP/IEDP = explosives/improvised explosive device precursors.
OSHA Process Safety Management (PSM) Standard List
|Chemical Name||CAS Number||Threshold Quantity (TQ)|
|Hydrogen Peroxide (52% by weight or greater)||7722-84-1||7500 pounds|
- HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE