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TRINITROCHLOROBENZENE (PICRYL CHLORIDE), [WETTED WITH NOT LESS THAN 10% WATER BY MASS]

4.1 - Flammable solid
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The Chemical Identifier fields include common identification numbers, the NFPA diamond, U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.
CAS Number UN/NA Number
  • 28260-61-9
  • 88-88-0
DOT Hazard Label USCG CHRIS Code
  • Flammable Solid
none
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
"Trinitrochlorobenzene (picryl chloride), wetted, with not less than 10% water by mass" is a white to yellow moist mass of crystals or a slurry. An explosive, but wetting lowers the risk of detonation. Dangerously explosive if allowed to dry out. The dry compound melts at 83-85°C, is denser than water and is insoluble in water. May be toxic by ingestion. Store tightly sealed (to protect from drying out) in a cool, ventilated place, away from acute fire hazards and easily oxidized materials. May be irritating to skin and mucous membranes.

The Hazard fields include special hazard alerts, air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
  • Explosive
  • Strong Oxidizing Agent
Air & Water Reactions
No rapid reaction with air No rapid reaction with water
Fire Hazard
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

Flammable/combustible material. May be ignited by heat, sparks or flames. DRIED OUT material may explode if exposed to heat, flame, friction or shock; treat as an explosive, refer to ERG Guide 112. Keep material wet with water or treat as an explosive, refer to ERG Guide 112. Runoff to sewer may create fire or explosion hazard. (ERG, 2016)
Health Hazard
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

Some are toxic and may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)
Reactivity Profile
"Trinitrochlorobenzene (picryl chloride), wetted, with not less than 10% water by mass" is a desensitized high explosive. Burns but may be difficult to ignite. Emits toxic fumes of NOx and explodes when heated to decomposition. Forms unstable salts with concrete, ammonia, bases and metals, particularly copper, lead and zinc. Incompatible with reducing agents and bases, and can explode upon immediate contact with such materials. Incompatible with oxidizing agents such as chlorates and nitrates.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...

  • Cellulose-Based Absorbents
  • Expanded Polymeric Absorbents

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.

LARGE SPILL: Consider initial evacuation for 500 meters (1/3 mile) in all directions.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)
Firefighting
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

CARGO FIRE: DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE! Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn. Do not move cargo or vehicle if cargo has been exposed to heat.

TIRE OR VEHICLE FIRE: Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt. If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum distance to prevent fire from spreading to cargo area. Pay special attention to tire fires as re-ignition may occur. Stand by, at a safe distance, with extinguisher ready for possible re-ignition. (ERG, 2016)
Non-Fire Response
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch or walk through spilled material.

SMALL SPILL: Flush area with flooding quantities of water.

LARGE SPILL: Wet down with water and dike for later disposal. KEEP "WETTED" PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF WATER. (ERG, 2016)
Protective Clothing
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from ERG Guide 113 [Flammable Solids - Toxic (Wet/Desensitized Explosive)]:

Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. (ERG, 2016)

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds. The information in CAMEO Chemicals comes from a variety of data sources.
Chemical Formula:
  • C6H2ClN3O6
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: data unavailable
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: data unavailable
Water Solubility: data unavailable
Ionization Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Trinitrochlorobenzene; (Picryl chloride) (28260-61-9) 30 mg/m3 330 mg/m3 2000 mg/m3
(DOE, 2016)

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Department of Homeland Security's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

No regulatory information available.

DHS Chemical Facility Anti-Terrorism Standards (CFATS)

RELEASE THEFT SABOTAGE
Chemical of Interest CAS Number Min Conc STQ Security
Issue
Min Conc STQ Security
Issue
Min Conc STQ Security
Issue
Trinitrochlorobenzene 88-88-0 ACG 5000 pounds explosive ACG 400 pounds EXP/IEDP

(DHS, 2007)

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

This section provides a listing of alternate names for this chemical, including trade names and synonyms.
  • 2-CHLORO-1,3,5-TRINITROBENZENE
  • CHLOROTRINITROBENZENE
  • TNCB
  • TRINITROCHLOROBENZENE
  • TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED
  • TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED IN ALCOHOL OR ETHER
  • TRINITROCHLOROBENZENE (PICRYL CHLORIDE), [WETTED WITH NOT LESS THAN 10% WATER BY MASS]
  • TRINITROCHLOROBENZENE, 2,4,6- (PICRYL CHLORIDE)
  • 2,4,6-TRINITROCHLOROBENZENE

Version 2.7.1