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PHENOXARSINE, 10,10'-OXYDI-

8 - Corrosive
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The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.
CAS Number UN/NA Number
  • 58-36-6
DOT Hazard Label USCG CHRIS Code
  • Corrosive
none
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
A clear light yellow liquid with a mild odor. Insoluble in water and slightly denser than water. Contact may severely irritate skin, eyes, and mucous membranes.

The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
  • Highly Flammable
Air & Water Reactions
Highly flammable. Insoluble in water.
Fire Hazard
(Non-Specific -- Arsenic Compounds) When heated to decomposition, it emits highly toxic fumes of arsenic. (EPA, 1998)
Health Hazard
(Non-Specific -- Arsenic Compounds) Arsenic compounds are acutely poisonous by ingestion. Ingestion or inhalation may result in chronic poisoning. Arsenic compounds are recognized carcinogens of the skin, lungs, and liver. (EPA, 1998)
Reactivity Profile
Organometallics, such as PHENOXARSINE, 10,10'-OXYDI-, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
(Non-Specific -- Arsenic Compound, Solid, n.o.s.) Stay upwind; keep out of low areas. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing.

(Non-Specific -- Arsenic Compound, Solid, n.o.s.) Small fires: dry chemical, carbon dioxide, water spray, or foam. Large fires: water spray, fog, or foam. Move container from fire area if you can do so without risk. (EPA, 1998)
Non-Fire Response
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Prevent entry into waterways, sewers, basements or confined areas. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS. (ERG, 2024)
Protective Clothing
For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. (EPA, 1998)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Warning: Effects usually appear within 30 to 60 minutes, but may be delayed for a few hours. Arsenic compounds are recognized carcinogens of the skin, lungs, and liver. Caution is advised.

Signs and Symptoms of Phenoxarsine, 10,10'-oxydi- Exposure: Signs and symptoms of acute exposure to phenoxarsine, 10,10'-oxydi may include dehydration, intense thirst, difficulty swallowing, nausea, vomiting, anorexia and abdominal pain. Headache, red conjunctival stains, and garlic breath are among the first signs and symptoms of poisoning. Exposure to airborne dust is generally accompanied by irritation of exposed skin, eyes, and mucous membranes. Conjunctivitis (red, inflamed eyes), runny nose, and lacrimation (tearing) are common. Pulmonary edema may also occur. Cardiovascular effects include shock, hypotension (low blood pressure), tachycardia (rapid heart rate), T-wave elevations, ventricular fibrillation, and other cardiac abnormalities. Jaundice and bronzing of the skin have been reported in severe hemolysis cases. Oliguria leading to anuria may result from hemoglobinuria; urine may become green or red in color. Altered mental status, seizures, and delirium are further complications of phenoxarsine, 10,10'-oxydi- exposure. Intense muscle cramping may be observed.

Emergency Life-Support Procedures: Acute exposure to phenoxarsine, 10,10'-oxydi- may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.

Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to phenoxarsine, 10,10'-oxydi-.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
4. Rush to a health care facility.

Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self-exposure to phenoxarsine,10,10'-oxydi-.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
3. Remove and isolate contaminated clothing and shoes as soon as possible.
4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5. Wash exposed skin areas thoroughly with water.
6. Obtain authorization and/or further instructions from the local hospital for performance of other invasive procedures.
7. Rush to a health care facility.

Ingestion Exposure:
1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer 100% humidified oxygen or other respiratory support.
2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
3. DO NOT induce vomiting.
4. Activated charcoal is of no value.
5. Rush to health care facility. (EPA, 1998)

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds The information in CAMEO Chemicals comes from a variety of data sources.

Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Chemical Formula:
  • C24H16As2O3
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: 363 to 365°F (EPA, 1998)
Vapor Pressure: data unavailable
Vapor Density (Relative to Air): data unavailable
Specific Gravity: data unavailable
Boiling Point: data unavailable
Molecular Weight: 502.23 (EPA, 1998)
Water Solubility: data unavailable
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Oxydiphenoxarsine, 10,10'-; (Phenoxarsine oxide) (58-36-6) 5 mg/m3 14 mg/m3 84 mg/m3
(DOE, 2024)

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
Arsenic Compounds N020 & 313
Phenoxarsine, 10,10'-oxydi- 58-36-6 500/10000 pounds 500 pounds 313c

(EPA List of Lists, 2024)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

This section provides a listing of alternate names for this chemical, including trade names and synonyms.
  • BIS(10-PHENOXARSINYL) OXIDE
  • BIS(10-PHENOXARSYL) OXIDE
  • BIS(PHENOXARSIN-10-YL) ETHER
  • BIS(PHENOXARSIN-10-YL)ETHER
  • 10,10'-BIS(PHENOXARSINYL) OXIDE
  • DID 47
  • DUROTEX
  • ESTABEX ABF
  • 10H-PHENOXARSINE, 10,10'-OXYBIS
  • INTERCIDE ABF 1 ESBO
  • OBPA
  • 10,10'-OXIDIPHENOXARSINE
  • 10,10'-OXYBISPHENOXARSINE
  • PHENOXARSINE, 10,10'-OXYDI-
  • SA 546
  • VINADINE
  • VINYZENE
  • VINYZENE (PESTICIDE)
  • VINYZENE BP 5
  • VINYZENE BP 5-2
  • VINYZENE BP 505
  • VINYZENE BS 1
  • VINYZENE SB 1
  • VINYZENE SB 1PS

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