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O-NITROANILINE

6.1 - Poison
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The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.
CAS Number UN/NA Number
  • 88-74-4
DOT Hazard Label USCG CHRIS Code
  • Poison
NIOSH Pocket Guide International Chem Safety Card
none
NFPA 704
Diamond Hazard Value Description
1
3 2
Blue Health 3 Can cause serious or permanent injury.
Red Flammability 1 Must be preheated before ignition can occur.
Yellow Instability 2 Readily undergoes violent chemical changes at elevated temperatures and pressures.
White Special
Note: NFPA ratings shown are for nitroanilines, CAS number 100-01-6.
(NFPA, 2010)
General Description
Orange solid with a musty odor. Sinks and mixes slowly with water. (USCG, 1999)

The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire. (USCG, 1999)
Health Hazard
Inhalation or ingestion causes headache, nausea, methemo- globinemia, vomiting, weakness, and stupor; cyanosis caused by contact usually develops in 4-6 hrs.; prolonged and excessive exposure may also cause liver damage. Contact with eyes or skin causes irritation; continued exposure may cause same symptoms as inhalation or ingestion. (USCG, 1999)
Reactivity Profile
O-NITROANILINE may be sensitive to prolonged exposure to light. Mixtures of this chemical with magnesium are hypergolic on contact with nitric acid. It forms extremely explosive addition compounds with hexanitroethane. It has a vigorous reaction with sulfuric acid above 392°F. It is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers. (NTP, 1992)
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

Use caution: Liquids with this reactive group classification have been known to react with the absorbents listed below. More info about absorbents, including situations to watch out for...

  • Cellulose-Based Absorbents
  • Expanded Polymeric Absorbents

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Fire Extinguishing Agents: Water, foam, dry chemical, carbon dioxide (USCG, 1999)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should keep this material in a tightly-closed container under an inert atmosphere, and store it at refrigerated temperatures. You should protect this chemical from exposure to light. (NTP, 1992)
Protective Clothing
Self-contained breathing apparatus; neoprene gauntlets; safety goggles; rubber or neoprene sealed-tongue work shoes and apron; close-weave cotton coveralls capable of closing at wrist and ankle (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds The information in CAMEO Chemicals comes from a variety of data sources.

Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Chemical Formula:
  • C6H6N2O2
Flash Point: 335°F (NTP, 1992)
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: 970°F (USCG, 1999)
Melting Point: 160.7°F (NTP, 1992)
Vapor Pressure: 1 mmHg at 219.2°F ; <0.1 mmHg at 86°F (NTP, 1992)
Vapor Density (Relative to Air): 4.77 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.44 at 68°F (USCG, 1999) - Denser than water; will sink
Boiling Point: 543°F at 760 mmHg (NTP, 1992)
Molecular Weight: 138.13 (NTP, 1992)
Water Solubility: less than 1 mg/mL at 70.7°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
Nitroaniline, 2-; (o-Nitroaniline) (88-74-4) 6.2 mg/m3 68 mg/m3 410 mg/m3
(DOE, 2018)

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

No regulatory information available.

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

This section provides a listing of alternate names for this chemical, including trade names and synonyms.
  • 1-AMINO-2-NITROBENZENE
  • 2-AMINONITROBENZENE
  • ANILINE, O-NITRO-
  • AZOENE FAST ORANGE GR BASE
  • AZOENE FAST ORANGE GR SALT
  • AZOFIX ORANGE GR SALT
  • AZOGENE FAST ORANGE GR
  • AZOIC DIAZO COMPONENT 6
  • BRENTAMINE FAST ORANGE GR BASE
  • BRENTAMINE FAST ORANGE GR SALT
  • C.I. 37025
  • C.I. AZOIC DIAZO COMPONENT 6
  • DEVOL ORANGE B
  • DEVOL ORANGE SALT B
  • DIAZO FAST ORANGE GR
  • FAST ORANGE BASE GR
  • FAST ORANGE BASE JR
  • FAST ORANGE GR BASE
  • FAST ORANGE GR SALT
  • FAST ORANGE O BASE
  • FAST ORANGE O SALT
  • FAST ORANGE SALT GR
  • FAST ORANGE SALT JR
  • HILTONIL FAST ORANGE GR BASE
  • HILTOSAL FAST ORANGE GR SALT
  • HINDASOL ORANGE GR SALT
  • NATASOL FAST ORANGE GR SALT
  • 1-NITRO-2-AMINOBENZENE
  • 2-NITROANILINE
  • 2-NITROBENZENAMINE
  • 2-NITROPHENYLAMINE
  • O-AMINONITROBENZENE
  • O-NITRANILINE
  • O-NITROANILINE
  • O-NITROPHENYLAMINE
  • ONA
  • ORANGE BASE CIBA II
  • ORANGE BASE IRGA II
  • ORANGE GRS SALT
  • ORANGE SALT CIBA II
  • ORANGE SALT IRGA II
  • ORTHONITROANILINE

Version 3.0.0