BERYLLIUM POWDER
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The
Chemical Identifier fields
include common identification numbers, the
NFPA diamond
U.S. Department of Transportation hazard labels, and a general
description of the chemical. The information in CAMEO Chemicals comes
from a variety of
data sources.
| CAS Number | UN/NA Number |
|---|---|
|
|
| DOT Hazard Label | USCG CHRIS Code |
|
|
| NIOSH Pocket Guide | International Chem Safety Card |
Beryllium & beryllium compounds (as Be)
|
NFPA 704
| Diamond | Hazard | Value | Description | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Health
|
3 | Can cause serious or permanent injury. | |||||||||
Flammability
|
1 | Must be preheated before ignition can occur. | ||||||||||
Instability
|
0 | Normally stable, even under fire conditions. | ||||||||||
Special
|
(NFPA, 2010)
General Description
A grayish-white hard light metal. Denser than water, but the powder may float. May be toxic by inhalation. Will burn if involved in a fire.
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The
Hazard fields
include
special hazard alerts
air and water
reactions, fire hazards, health hazards, a reactivity profile, and
details about
reactive groups assignments
and
potentially incompatible absorbents.
The information in CAMEO Chemicals comes from a variety of
data sources.
Reactivity Alerts
- Highly Flammable
- Strong Reducing Agent
Air & Water Reactions
Insoluble in water. Beryllium is a flammable solid that will ignite if its surroundings are on fire. It can react with water under fire conditions, but is unlikely to do so otherwise.
Fire Hazard
Special Hazards of Combustion Products: Combustion yields beryllium oxide fume, which is toxic if inhaled.
Behavior in Fire: Powder may form explosive mixture with air. (USCG, 1999)
Behavior in Fire: Powder may form explosive mixture with air. (USCG, 1999)
Health Hazard
Any dramatic, unexplained weight loss should be considered as possible first indication of beryllium disease. Dust is extremely toxic when inhaled; symptoms include coughing, shortness of breath, and acute or chronic lung disease. There is no record of illness from ingestion of beryllium. Contact with dust causes conjunctival inflammation of eyes and dermatitis. (USCG, 1999)
Reactivity Profile
Boron trifluoride reacts with incandescence when heated with alkali metals or alkaline earth metals except magnesium [Merck 11th ed. 1989]. Finely divided or amalgamated metal reacts with HCl, dil HNO3, or dil H2SO4; attacked by strong base with evolution of hydrogen gas [Merck 11th ed. 1989]. It has been determined experimentally that a mixture of beryllium powder with carbon tetrachloride or with trichloroethylene will flash or spark on heavy impact [ASESB Pot. Incid. 39 1968]. The reaction between beryllium and the vapors of phosphorus proceeds with incandescence [Mellor 8:842 1946-47].
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents
No information available.
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The
Response Recommendation fields
include isolation and evacuation distances, as well as recommendations for
firefighting, non-fire response, protective clothing, and first aid. The
information in CAMEO Chemicals comes from a variety of
data sources.
Isolation and Evacuation
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 25 meters (75 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 25 meters (75 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2020)
Firefighting
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Avoid aiming straight or solid streams directly onto the product. Do not get water inside containers. Dike runoff from fire control for later disposal.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)
SMALL FIRE: Dry chemical, CO2, water spray or alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Avoid aiming straight or solid streams directly onto the product. Do not get water inside containers. Dike runoff from fire control for later disposal.
FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2020)
Non-Fire Response
Excerpt from ERG Guide 134 [Flammable Solids - Toxic and/or Corrosive]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Stop leak if you can do it without risk. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Prevent entry into waterways, sewers, basements or confined areas. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2020)
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. Stop leak if you can do it without risk. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Prevent entry into waterways, sewers, basements or confined areas. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2020)
Protective Clothing
Excerpt from NIOSH Pocket Guide for Beryllium & beryllium compounds (as Be):
Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: DAILY - The worker should wash daily at the end of each work shift, and prior to eating, drinking, smoking, etc.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.
Provide: EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection. (NIOSH, 2023)
:Skin: PREVENT SKIN CONTACT - Wear appropriate personal protective clothing to prevent skin contact.
Eyes: PREVENT EYE CONTACT - Wear appropriate eye protection to prevent eye contact.
Wash skin: DAILY - The worker should wash daily at the end of each work shift, and prior to eating, drinking, smoking, etc.
Remove: WHEN WET OR CONTAMINATED - Work clothing that becomes wet or significantly contaminated should be removed and replaced.
Change: DAILY - Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises.
Provide: EYEWASH - Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances; this is irrespective of the recommendation involving the wearing of eye protection. (NIOSH, 2023)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
Excerpt from NIOSH Pocket Guide for Beryllium & beryllium compounds (as Be):
Eye: IRRIGATE IMMEDIATELY - If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
Breathing: FRESH AIR - If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. (NIOSH, 2023)
:Eye: IRRIGATE IMMEDIATELY - If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately.
Breathing: FRESH AIR - If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. Other measures are usually unnecessary. (NIOSH, 2023)
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The
Physical Property fields
include properties such as vapor pressure and
boiling point, as well as explosive limits and
toxic exposure thresholds
The information in CAMEO Chemicals comes from a variety of
data sources.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
| Chemical Formula: |
|
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point:
2349°F
(NIOSH, 2023)
Vapor Pressure:
0 mmHg
(approx)
(NIOSH, 2023)
Vapor Density (Relative to Air): data unavailable
Specific Gravity:
1.85
at 68°F
(USCG, 1999)
- Denser than water; will sink
Boiling Point:
4532°F
at 760 mmHg
(NIOSH, 2023)
Molecular Weight:
9.01
(USCG, 1999)
Water Solubility:
Insoluble
(NIOSH, 2023)
Ionization Energy/Potential: data unavailable
IDLH:
4 mg Be/m3
; A potential occupational carcinogen.
(NIOSH, 2023)
AEGLs (Acute Exposure Guideline Levels)
No AEGL information available.ERPGs (Emergency Response Planning Guidelines)
| Chemical | ERPG-1 | ERPG-2 | ERPG-3 |
|---|---|---|---|
| Beryllium (7440-41-7) | NA | 0.025 mg/m3 | 0.1 mg/m3 |
NA = not appropriate.
(AIHA, 2022)
PACs (Protective Action Criteria)
| Chemical | PAC-1 | PAC-2 | PAC-3 |
|---|---|---|---|
| Beryllium (7440-41-7) | 0.0023 mg/m3 | 0.025 mg/m3 | 0.1 mg/m3 |
(DOE, 2018)
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The
Regulatory Information fields
include information from
the U.S. Environmental Protection Agency's Title III Consolidated List of
Lists,
the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility
Anti-Terrorism Standards,
and the U.S. Occupational Safety and Health Administration's
Process Safety Management of Highly Hazardous Chemicals Standard List
(see more about these
data sources).
EPA Consolidated List of Lists
| Regulatory Name | CAS Number/ 313 Category Code |
EPCRA 302 EHS TPQ |
EPCRA 304 EHS RQ |
CERCLA RQ | EPCRA 313 TRI |
RCRA Code |
CAA 112(r) RMP TQ |
|---|---|---|---|---|---|---|---|
| Beryllium †† | 7440-41-7 | 10 pounds | 313 | P015 | |||
| Beryllium Compounds | N050 | & | 313 |
- †† indicates that no reporting of releases of this CERCLA hazardous substance is required under CERCLA if the diameter of the pieces of the solid metal released is larger than 100 micrometers (0.004 inches).
- & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. See 50 Federal Register 13456 (April 4, 1985).
(EPA List of Lists, 2022)
CISA Chemical Facility Anti-Terrorism Standards (CFATS)
No regulatory information available.OSHA Process Safety Management (PSM) Standard List
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This section provides a listing of alternate names for this chemical,
including trade names and synonyms.
- BERYLLIUM
- BERYLLIUM ATOM
- BERYLLIUM ELEMENT
- BERYLLIUM METAL: BERYLLIUM
- BERYLLIUM POWDER
- BERYLLIUM, (DUST OR POWDER), METAL
- BERYLLIUM, [POWDER]
- BERYLLIUM-9
- GLUCINIUM
Version 3.0.0