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DICHLORODIPHENYLDICHLOROETHANE

6.1 - Poison
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The Chemical Identifier fields include common identification numbers, the NFPA diamond U.S. Department of Transportation hazard labels, and a general description of the chemical. The information in CAMEO Chemicals comes from a variety of data sources.
CAS Number UN/NA Number
  • 72-54-8
DOT Hazard Label USCG CHRIS Code
  • Poison
NIOSH Pocket Guide International Chem Safety Card
none none
NFPA 704
data unavailable
General Description
A colorless crystalline solid. Insoluble in water and sinks in water. Toxic by inhalation, skin absorption or ingestion. Used as a pesticide.

The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. The information in CAMEO Chemicals comes from a variety of data sources.
Reactivity Alerts
none
Air & Water Reactions
Insoluble in water.
Fire Hazard
Special Hazards of Combustion Products: Irritating hydrogen chloride fumes may form in fires. (USCG, 1999)
Health Hazard
SYMPTOMS: Symptoms of exposure to this compound may include anorexia, nausea, vomiting, diarrhea, dermatitis, apathy from mild dulling of interest to profound psychotic depression, gynecomastia, hematuria, leukopenia, thrombocytopenia and lassitude. It may cause slight irritation of the skin and lethargy. Chronic exposure may cause atrophy of the adrenal cortex and liver damage.

ACUTE/CHRONIC HAZARDS: This compound is toxic by skin absorption. It may cause slight irritation of the skin. When heated to decomposition this compound emits toxic fumes of chlorides, carbon monoxide, carbon dioxide and hydrogen chloride gas. (NTP, 1992)
Reactivity Profile
DICHLORODIPHENYLDICHLOROETHANE is a halogenated hydrocarbon. Compounds in this group may react with acids, bases, and oxidizing and reducing agents. They are incompatible with alkali, and strong oxidizers, in particular.
Belongs to the Following Reactive Group(s)
Potentially Incompatible Absorbents

No information available.

The Response Recommendation fields include isolation and evacuation distances, as well as recommendations for firefighting, non-fire response, protective clothing, and first aid. The information in CAMEO Chemicals comes from a variety of data sources.
Isolation and Evacuation
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.

SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.

FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Firefighting
Fire Extinguishing Agents: Water, foam, dry chemical, carbon dioxide (USCG, 1999)
Non-Fire Response
SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should store this chemical under ambient temperatures, and keep it away from oxidizing materials. (NTP, 1992)
Protective Clothing
Dust mask; goggles or face shield; rubber gloves (USCG, 1999)
DuPont Tychem® Suit Fabrics
No information available.
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

The Physical Property fields include properties such as vapor pressure and boiling point, as well as explosive limits and toxic exposure thresholds The information in CAMEO Chemicals comes from a variety of data sources.

Note: For Vapor Density and Specific Gravity, comparing the value to 1.0 can tell you if the chemical will likely sink/rise in air or sink/float in fresh water (respectively). Short phrases have been added to those values below as an aid. However, make sure to also consider the circumstances of a release. The Vapor Density comparisons are only valid when the gas escaping is at the same temperature as the surrounding air itself. If the chemical is escaping from a container where it was pressurized or refrigerated, it may first escape and behave as a heavy gas and sink in the air (even if it has a Vapor Density value less than 1). Also, the Specific Gravity comparisons are for fresh water (density 1.0 g/mL). If your spill is in salt water (density about 1.027 g/mL), you need to adjust the point of comparison. There are some chemicals that will sink in fresh water and float in salt water.
Chemical Formula:
  • C14H10Cl4
Flash Point: data unavailable
Lower Explosive Limit (LEL): data unavailable
Upper Explosive Limit (UEL): data unavailable
Autoignition Temperature: data unavailable
Melting Point: 228 to 230°F (NTP, 1992)
Vapor Pressure: 1e-06 mmHg at 86°F (NTP, 1992)
Vapor Density (Relative to Air): 11 (NTP, 1992) - Heavier than air; will sink
Specific Gravity: 1.385 (NTP, 1992) - Denser than water; will sink
Boiling Point: 379°F at 760 mmHg (NTP, 1992)
Molecular Weight: 350.46 (NTP, 1992)
Water Solubility: less than 1 mg/mL at 65.3°F (NTP, 1992)
Ionization Energy/Potential: data unavailable
IDLH: data unavailable

AEGLs (Acute Exposure Guideline Levels)

No AEGL information available.

ERPGs (Emergency Response Planning Guidelines)

No ERPG information available.

PACs (Protective Action Criteria)

Chemical PAC-1 PAC-2 PAC-3
DDD; (1,1-bis(4-Chlorophenyl)-2,2-dichloroethane) (72-54-8) 2.4 mg/m3 26 mg/m3 160 mg/m3
(DOE, 2024)

The Regulatory Information fields include information from the U.S. Environmental Protection Agency's Title III Consolidated List of Lists, the U.S. Cybersecurity and Infrastructure Security Agency's Chemical Facility Anti-Terrorism Standards, and the U.S. Occupational Safety and Health Administration's Process Safety Management of Highly Hazardous Chemicals Standard List (see more about these data sources).

EPA Consolidated List of Lists

Regulatory Name CAS Number/
313 Category Code
EPCRA 302
EHS TPQ
EPCRA 304
EHS RQ
CERCLA RQ EPCRA 313
TRI
RCRA
Code
CAA 112(r)
RMP TQ
DDD 72-54-8 1 pound U060

(EPA List of Lists, 2024)

CISA Chemical Facility Anti-Terrorism Standards (CFATS)

No regulatory information available.

OSHA Process Safety Management (PSM) Standard List

No regulatory information available.

This section provides a listing of alternate names for this chemical, including trade names and synonyms.
  • 2,2-BIS(4-CHLOROPHENYL)-1,1-DICHLOROETHANE
  • 1,1-BIS(4-CHLOROPHENYL)-2,2-DICHLOROETHANE
  • 2,2-BIS(P-CHLOROPHENYL)-1,1-DICHLOROETHANE
  • 1,1-BIS(P-CHLOROPHENYL)-2,2-DICHLOROETHANE
  • 2,2-BIS(P-CHLOROPHENYL-1,1-DICHLOROETHANE
  • DDD
  • DDD (ANALYTICAL)
  • 4,4'-DDD
  • 1,1-DICHLORO-2,2-BIS(4-CHLOROPHENYL)ETHANE
  • 1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL) ETHANE
  • 1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL)ETHANE
  • 1,1-DICHLORO-2,2-BIS(PARACHLOROPHENYL)ETHANE
  • 1,1-DICHLORO-2,2-DI(4-CHLOROPHENYL)ETHANE
  • DICHLORODIPHENYL DICHLOROETHANE
  • DICHLORODIPHENYLDICHLOROETHANE
  • DILENE
  • ENT 4,225
  • ETHANE, 1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL)-
  • ME 1700
  • NCI-C00475
  • OMS 1078
  • P,P'-DDD
  • P,P'-DICHLORODIPHENYLDICHLOROETHANE
  • P,P'-DICHLORODIPHENYLETHYLENE DICHLORIDE
  • P,P'-TDE
  • RHOTHANE
  • RHOTHANE D-3
  • ROTHANE
  • TDE
  • TDE (1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL) ETHANE)
  • TDE (1,1-DICHLORO-2,2-BIS(P-CHLOROPHENYL)ETHANE)
  • 4,4'-TDE
  • TETRACHLORODIPHENYLETHANE

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