Acrylates and Acrylic Acids
There are 61 chemical datasheets assigned to this reactive group.
Reactive groups are categories of chemicals that typically react in similar ways because they are similar in their chemical structure. Each substance with a chemical datasheet has been assigned to one or more reactive groups, and CAMEO Chemicals uses the reactive group assignments to make its reactivity predictions. More info about reactivity predictions...
If you can't find a chemical in the database--but you know what reactive group it belongs in--you can add the reactive group to MyChemicals instead in order to see the reactivity predictions.
These materials are capable of thermally induced or chemically initiated radical type polymerization reactions which can generate significant amounts of heat (up to -100 kJ/mol). This can result in large adiabatic temperature rises, which also can trigger gassy decomposition reactions.
These materials are typically inhibited with low levels (ppm range) of antioxidants to prevent premature polymerization chain reactions and these inhibitors may require dissolved oxygen to be effective. The inhibitors can be depleted with time and are depleted faster at higher storage temperatures. These materials are known to be susceptible to destabilization due to contaminants, even at low levels of contamination. Although there are obvious contaminants that are known to possibly be immediately initiatory to the monomer (radical generating species such as peroxides, azides, etc.), other effects on stability from even seemingly benign materials are harder to predict. Therefore extreme caution should be used in any contamination event and the material should be presumed to be destabilized until testing and consultation with experts occurs and determines otherwise. If the inhibitor and inhibition mechanism are compromised via some interaction with the contaminant, the monomer may polymerize and if contained in a storage container at relatively large volume, the system may become adiabatic and lead to a serious runaway reaction with high temperatures and pressures. The general hazards of monomers are discussed in Frurip et al., Process Safety Progress (Vol. 14, No. 2) 1995.
Use the links below to find out how this reactive group interacts with any of the reactive groups in the database.
The predicted hazards and gas byproducts for each reactive group pair will be displayed, as well as documentation and references that were used to make the reactivity predictions.
- Acetals, Ketals, Hemiacetals, and Hemiketals
- Acids, Carboxylic
- Acids, Strong Non-oxidizing
- Acids, Strong Oxidizing
- Acids, Weak
- Acrylates and Acrylic Acids
- Acyl Halides, Sulfonyl Halides, and Chloroformates
- Alcohols and Polyols
- Aldehydes
- Alkynes, with Acetylenic Hydrogen
- Alkynes, with No Acetylenic Hydrogen
- Amides and Imides
- Amines, Aromatic
- Amines, Phosphines, and Pyridines
- Anhydrides
- Aryl Halides
- Azo, Diazo, Azido, Hydrazine, and Azide Compounds
- Bases, Strong
- Bases, Weak
- Carbamates
- Carbonate Salts
- Chlorosilanes
- Conjugated Dienes
- Cyanides, Inorganic
- Diazonium Salts
- Epoxides
- Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
- Ethers
- Fluoride Salts, Soluble
- Fluorinated Organic Compounds
- Halogenated Organic Compounds
- Halogenating Agents
- Hydrocarbons, Aliphatic Saturated
- Hydrocarbons, Aliphatic Unsaturated
- Hydrocarbons, Aromatic
- Insufficient Information for Classification
- Isocyanates and Isothiocyanates
- Ketones
- Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
- Metals, Alkali, Very Active
- Metals, Elemental and Powder, Active
- Metals, Less Reactive
- Nitrate and Nitrite Compounds, Inorganic
- Nitrides, Phosphides, Carbides, and Silicides
- Nitriles
- Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic
- Non-Redox-Active Inorganic Compounds
- Not Chemically Reactive
- Organometallics
- Oxidizing Agents, Strong
- Oxidizing Agents, Weak
- Oximes
- Peroxides, Organic
- Phenolic Salts
- Phenols and Cresols
- Polymerizable Compounds
- Quaternary Ammonium and Phosphonium Salts
- Reducing Agents, Strong
- Reducing Agents, Weak
- Salts, Acidic
- Salts, Basic
- Siloxanes
- Sulfides, Inorganic
- Sulfides, Organic
- Sulfite and Thiosulfate Salts
- Sulfonates, Phosphonates, and Thiophosphonates, Organic
- Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts
- Water and Aqueous Solutions
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